The photoelectric effect occurs when light (or more generally, electromagnetic radiation) incident on a metallic surface causes the ejection of electrons from the surface.
The energy of the incident photons must be greater than the work function of the metal (denoted by
) for the electrons to be ejected.
The energy of the ejected electrons can be expressed as the difference between the energy of the incident photons and the work function of the metal.
The maximum kinetic energy of the ejected electrons is given by:
Kmax=hν−ϕ0 where
is the Planck's constant, ν is the frequency of the incident light, and
is the work function of the metal. We can also write the maximum kinetic energy in terms of the stopping potential (
) and the elementary charge (
) of an electron:
Kmax=eV0 Equating these two expressions for the maximum kinetic energy, we get:
eV0=hν−ϕ0 We can express the frequency ν in terms of the speed of light
and the wavelength λ:
ν=λc Substituting this expression for frequency in the equation, we get:
eV0=hλc−ϕ0 Now, we have two cases: The stopping potential is
, and the wavelength is λ. The stopping potential is
, and the wavelength is
. For the first case, we use the photoelectric effect equation as is:
eV0=λhc−ϕ0 For the second case, we replace
with
and λ with
:
4eV0=2λhc−ϕ0 Now we have two equations: (1)
eV0=λhc−ϕ0 (2)
4eV0=2λhc−ϕ0 We can rewrite equation (1) as:
4eV0=4λhc−4ϕ0 Now we can equate the two expressions for
:
4λhc−4ϕ0=2λhc−ϕ0 Now we isolate the terms containing
:
43ϕ0=4λhc−2λhc 43ϕ0=4λhc Now we can write the work function
in terms of the threshold wavelength
:
ϕ0=λ0hc Substituting the expression for the work function
in terms of the threshold wavelength
into the previous equation, we get:
43λ0hc=4λhc Now we can cancel out the common terms
from both sides:
4λ03=4λ1 Next, we can cross-multiply to solve for
:
3λ=λ0 Thus, the threshold wavelength for this metallic surface is
.