p-Block Elements

NEET Chemistry · 114 questions · Page 12 of 12 · Click an option or "Show Solution" to reveal answer

Q111
Which one of the following statements is not true?
A Among halide ions, iodide is the most powerful reducing agent.
B Fluorine is the only halogen that does not show a variable oxidation state.
C HOCl is a stronger acid than HOBr.
D HF is a stronger acid than HCl.
Correct Answer
Option D
Solution

F is more electronegative than Cl therefore HF bond is stronger than HCl and hence proton is not given off easily and hence HF is a weakest acid.

Q112
Which one of the following compounds is not a protonic acid?
A B(OH) 3
B PO(OH) 3
C SO(OH) 2
D SO 2 (OH) 2
Correct Answer
Option A
Solution

B(OH) 3 does not provide H + ions in water instead it accepts OH – ion and hence it is Lewis acid.

B(OH) 3 + H 2 O ⇌ [B(OH) 4 ] - + H +

Q113
Which of the following statement is true?
A Silicon exhibits 4 coordination number in its compound.
B Bond energy of F 2 is less than Cl 2 .
C Mn(III) oxidation state is more stable than Mn(II) in aqueous state.
D Elements of 15 th group shows only + 3 and +5 oxidation states.
Correct Answer
Option B
Solution

Fluorine is more reactive than chlorine.

So, bond energy of chlorine is greater than fluorine.

Silicon exhibits 6 coordination numbers.

In aqueous state Mn(II) is more stable.

Mn ⇌ Mn 2+ + 2e -

Q114
Which compound is electron deficient?
A BeCl 2
B BCl 3
C CCl 4
D PCl 5
Correct Answer
Option B
Solution

In BCl 3 the central atom ‘B’ is sp 2 hybridised and contains only ‘six’ electrons in its valence shell.

Therefore it is electron deficient.

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