Heat and Thermodynamics

JEE Physics · 315 questions · Page 1 of 32 · Click an option or "Show Solution" to reveal answer

Q1
Identify the characteristics of an adiabatic process in a monoatomic gas. (A) Internal energy is constant. (B) Work done in the process is equal to the change in internal energy. (C) The product of temperature and volume is a constant. (D) The product of pressure and volume is a constant. (E) The work done to change the temperature from T1\mathrm{T}_1 to T2\mathrm{T}_2 is proportional to (T2T1)\left(\mathrm{T}_2-\mathrm{T}_1\right). Choose the correct answer from the options given below :
A (B), (D) only
B (B), (E) only
C (A), (C), (E) only
D (A), (C), (D) only
Correct Answer
Option B
Solution

In an adiabatic process, the key characteristics for a monoatomic gas are: No Heat Exchange: The adiabatic process occurs without heat transfer, meaning Q=0 Q = 0 .

Work Done and Internal Energy Change: The work done on or by the system is equal to the change in internal energy.

Mathematically, this is expressed as: ΔU=W \Delta U = -W where ΔU\Delta U is the change in internal energy and WW is the work done.

Work and Temperature Relationship: The work done when changing the temperature from T1 T_1 to T2 T_2 is proportional to the difference between these temperatures.

This relationship can be expressed as: Work Done=nCvΔT(T2T1) |\text{Work Done}| = nC_v \Delta T \propto (T_2 - T_1) Here, n n is the number of moles, Cv C_v is the molar heat capacity at constant volume, and ΔT\Delta T is the change in temperature.

From these characteristics, the correct features of an adiabatic process in a monoatomic gas relate to the relationships involving work done and temperature change, specifically options (B) and (E).

Q2
Each side of a box made of metal sheet in cubic shape is 'a' at room temperature 'T', the coefficient of linear expansion of the metal sheet is 'α\alpha'. The metal sheet is heated uniformly, by a small temperature Δ\DeltaT, so that its new temperature is T + Δ\DeltaT. Calculate the increase in the volume of the metal box.
A 3a3α\alphaΔ\DeltaT
B 4π\pia3α\alphaΔ\DeltaT
C 43{{4 \over 3}}π\pia3α\alphaΔ\DeltaT
D 4a3α\alphaΔ\DeltaT
Correct Answer
Option A
Solution

We know that,

γ=3α\gamma = 3\alpha

.... (i) where, α\alpha is the coefficient of linear expansion and γ\gamma is the coefficient of volume expansion.

We know that,

ΔVV=γΔT{{\Delta V} \over V} = \gamma \Delta T
ΔVV=3αΔT\Rightarrow {{\Delta V} \over V} = 3\alpha \Delta T

[from Eq. (i)]

ΔV=3a3αΔT\Delta V = 3{a^3}\alpha \Delta T

[ \because volume of cube = a3 ]

Q3
If Cp{C_p} and Cv{C_v} denote the specific heats of nitrogen per unit mass at constant pressure and constant volume respectively, then
A CpCv=28R{C_p} - {C_v} = 28R
B CpCv=R/28{C_p} - {C_v} = R/28
C CpCv=R/14{C_p} - {C_v} = R/14
D CpCv=R{C_p} - {C_v} = R
Correct Answer
Option B
Solution

According to Mayer's relationship

CpCv=R{C_p} - {C_v} = R

\therefore

CpMCvM=RM{{{C_p}} \over M} - {{{C_v}} \over M} = {R \over M}
\,\,\,\,\,\,

Here

M=28.M=28.
Q4
Two different wires having lengths L1 and L2, and respective temperature coefficient of linear expansion α\alpha 1 and α\alpha 2, are joined end-to-end. Then the effective temperature coefficient of linear expansion is :
A 2α1α22\sqrt {{\alpha _1}{\alpha _2}}
B 4α1α2α1+α2L2L1(L2+L1)24{{{\alpha _1}{\alpha _2}} \over {{\alpha _1} + {\alpha _2}}}{{{L_2}{L_1}} \over {{{\left( {{L_2} + {L_1}} \right)}^2}}}
C α1+α22{{{\alpha _1} + {\alpha _2}} \over 2}
D α1L1+α2L2L1+L2{{{\alpha _1}{L_1} + {\alpha _2}{L_2}} \over {{L_1} + {L_2}}}
Correct Answer
Option D
Solution

L'1 = L1(1 + α\alpha1

Δ\Delta

T) L'2 = L2(1 + α\alpha2

Δ\Delta

T) L'eq = (L1 + L2) (1 + α\alphaavg

Δ\Delta

T) \therefore (L1 + L2) (1 + α\alphaavg

Δ\Delta

T) = L1(1 + α\alpha1

Δ\Delta

T) + L2(1 + α\alpha2

Δ\Delta

T) \Rightarrow (L1 + L2)α\alphaavg = L1α\alpha1 + L2α\alpha2 \Rightarrow α\alphaavg =

α1L1+α2L2L1+L2{{{\alpha _1}{L_1} + {\alpha _2}{L_2}} \over {{L_1} + {L_2}}}
Q5
Assuming the Sun to be a spherical body of radius RR at a temperature of TKTK, evaluate the total radiant powered incident of Earth at a distance rr from the Sun Where r0 is the radius of the Earth and σ\sigma is Stefan's constant.
A 4πr02R2σT4r24\pi r_0^2{R^2}\sigma {{{T^4}} \over {{r^2}}}
B πr02R2σT4r2\pi r_0^2{R^2}\sigma {{{T^4}} \over {{r^2}}}
C r02R2σT44πr2r_0^2{R^2}\sigma {{{T^4}} \over {4\pi {r^2}}}
D R2σT4r2{R^2}\sigma {{{T^4}} \over {{r^2}}}
Correct Answer
Option B
Solution

Total power radiated by Sun

=σT4×4πR2= \sigma {T^4} \times 4\pi {R^2}

The intensity of power at earth's surface

=σT4×4πR24πr2= {{\sigma {T^4} \times 4\pi {R^2}} \over {4\pi {r^2}}}

Total power received by Earth

=σT4R2r2(πr02)= {{\sigma {T^4}{R^2}} \over {{r^2}}}\left( {\pi r_0^2} \right)
Q6
An ideal gas occupies a volume of 2m3 at a pressure of 3 × \times 106 Pa. The energy of the gas is :
A 6 × \times 104 J
B 9× \times 106 J
C 3 × \times 102 J
D 108 J
Correct Answer
Option B
Solution

Energy =

12{1 \over 2}

nRT =

f2{f \over 2}

PV =

f2{f \over 2}

(3 ×\times 106) (2) = f ×\times 3 ×\times 106 Considering gas is monoatomic i.e. f = 3 E. = 9 ×\times 106 J

Q7
A flask contains argon and oxygen in the ratio of 3 : 2 in mass and the mixture is kept at 27^\circC. The ratio of their average kinetic energy per molecule respectively will be :
A 3 : 2
B 9 : 4
C 2 : 3
D 1 : 1
Correct Answer
Option D
Solution
KEavg=32kTK{E_{avg}} = {3 \over 2}kT

(At lower temperature) As temperature is same for both the gases.

\Rightarrow Both gases will have same average kinetic energy.

(KEavg)argon(KEavg)oxygen=11\Rightarrow {{{{(K{E_{avg}})}_{\arg on}}} \over {{{(K{E_{avg}})}_{oxygen}}}} = {1 \over 1}
Q8
An ideal gas has molecules with 5 degrees of freedom. The ratio of specific heats at constant pressure (Cp ) and at constant volume (Cv) is :
A 6
B 72{7 \over 2}
C 52{5 \over 2}
D 75{7 \over 5}
Correct Answer
Option D
Solution

For ideal gas molecule with 5 degree of freedom, Cv =

52{5 \over 2}

R and Cp =

72{7 \over 2}

R

\therefore\,\,\,
CpCv{{{C_p}} \over {{C_v}}}

=

72R52R{{{7 \over 2}R} \over {{5 \over 2}R}}

=

75{7 \over 5}
Q9
One mole of an ideal monoatomic gas is compressed isothermally in a rigid vessel to double its pressure at room temperature, 27C.{27^ \circ }C. The work done on the gas will be :
A 300300 RR
B 300300 RR lnln 66
C 300300 RR lnln 22
D 300300 RR lnln 77
Correct Answer
Option C
Solution

We know, Work done on gas = nRT

\ell

n

(PfPi)\left( {{{{P_f}} \over {{P_i}}}} \right)

Given Pf = 2Pi T = 27 + 273 = 300 K and for monoatomic gas, n = 1.

\therefore\,\,\,\,

Work done = 1 ×\timesR ×\times300

\ell

n(2) = 300 R

\ell

n(2)

Q10
For a given gas at 1 atm pressure, rms speed of the molecule is 200 m/s at 127°C. At 2 atm pressure and at 227°C, the rms speed of the molecules will be :
A 100 m/s
B 100 5\sqrt 5 m/s
C 80 5\sqrt 5 m/s
D 80 m/s
Correct Answer
Option B
Solution
Vrms=3RTMw{V_{rms}} = \sqrt {{{3RT} \over {{M_w}}}}
VrmsT\Rightarrow {V_{rms}} \propto \sqrt T

Now,

v200=500400{v \over {200}} = \sqrt {{{500} \over {400}}}
v200=52\Rightarrow {v \over {200}} = {{\sqrt 5 } \over 2}
v=1005\Rightarrow v = 100\sqrt 5

m/s

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